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Supercritical Fluid Chromatography - Quiz
Contributed by: Porter
  • 1. Which of the following is commonly used as the mobile phase in SFC?
A) Acetone
B) Carbon dioxide
C) Methanol
D) Water
  • 2. What state is the mobile phase in SFC?
A) Solid
B) Supercritical
C) Liquid
D) Gas
  • 3. What is the mechanism of separation in SFC based on?
A) Differences in solubility in the mobile phase
B) Differences in molecular weight
C) Differences in conductivity
D) Differences in boiling point
  • 4. What is the purpose of using a back pressure regulator in SFC?
A) Enhance detector sensitivity
B) Avoid solvent contamination
C) Maintain supercritical conditions
D) Increase column temperature
  • 5. What advantage does SFC offer over traditional HPLC?
A) Higher resolution
B) Faster separation
C) Limited application range
D) Lower equipment cost
  • 6. What role does co-solvent play in SFC separations?
A) Improves stationary phase selectivity
B) Reduces detector interference
C) Stabilizes column efficiency
D) Enhances analyte solubility
  • 7. Which term describes the region where the mobile phase in SFC exhibits properties of both a liquid and a gas?
A) Supercritical zone
B) Transition zone
C) Near-critical region
D) Critical point
  • 8. At supercritical conditions, the density of carbon dioxide is similar to that of which phase?
A) Gas
B) Liquid
C) Aqueous
D) Solid
  • 9. How can the properties of a supercritical fluid be adjusted?
A) By altering its chemical composition.
B) Through exposure to light.
C) By changing the pressure and temperature, allowing fine-tuning between liquid-like and gas-like states.
D) By adding impurities.
  • 10. Under what condition can a binary mixture of supercritical fluids form two immiscible gas phases?
A) Only when both components have identical critical points.
B) When one component is much more volatile than the other, at high pressure and temperatures above the component critical points.
C) At low pressures regardless of temperature.
D) In all binary mixtures without exception.
  • 11. How can the critical point of a binary mixture be estimated?
A) As the arithmetic mean of the critical temperatures and pressures of the two components.
B) It cannot be estimated; it must always be measured experimentally.
C) By summing the critical points of each component.
D) Using only the critical temperature of one component.
  • 12. What methods can provide greater accuracy in calculating the critical point of a binary mixture?
A) Using only empirical observations without calculations.
B) By averaging the boiling points of the components.
C) Through direct measurement at all possible pressures and temperatures.
D) Equations of state, such as the Peng–Robinson or group-contribution methods.
  • 13. What separates the gas and liquid region in a pressure-temperature phase diagram?
A) The critical point
B) The density-pressure line
C) The melting curve
D) The boiling curve
  • 14. What is the surface temperature of Venus in Kelvin?
A) 300 K
B) 273 K
C) 735 K
D) 500 K
  • 15. Why does supercritical water electrolysis improve electrical efficiency?
A) It increases the volume of hydrogen produced.
B) It decreases the need for catalysts.
C) It eliminates bubbles on electrodes, reducing ohmic losses.
D) It uses less energy to heat the water.
  • 16. What is a necessary condition for effective supercritical water hydrolysis?
A) A continuous reaction system must be devised due to very short reaction times.
B) Supercritical conditions can only be achieved at low pressures.
C) Large amounts of water are needed to maintain the reaction.
D) The process requires long reaction times to be effective.
  • 17. What is the surface pressure on Venus in megapascals?
A) 9.3 megapascals
B) 1.0 megapascal
C) 5.0 megapascals
D) 12.0 megapascals
  • 18. Who discovered the critical point of a substance in 1822?
A) James Prescott Joule
B) Michael Faraday
C) Benjamin Thompson
D) Baron Charles Cagniard de la Tour
  • 19. What gases are primarily produced during supercritical water gasification?
A) O2, N2, Ar
B) Neon, Krypton, Xenon
C) H2, CH4, CO2, CO
D) NH3, SO2, NOx
  • 20. What happens to lignin during supercritical water hydrolysis?
A) Aliphatic inter-ring linkages are cleaved into low molecular weight mixed phenols.
B) Lignin is completely converted into simple sugars.
C) Lignin remains unchanged due to short reaction times.
D) Lignin forms a protective layer around polysaccharides.
  • 21. What property does CO2 exhibit at high pressures that is useful for various applications?
A) Reduced density
B) Increased viscosity
C) Antimicrobial properties
D) Enhanced conductivity
  • 22. What is one proposed application of supercritical carbon dioxide in power generation?
A) Rankine cycle
B) The Allam cycle
C) Otto cycle
D) Brayton cycle
  • 23. In which field has supercritical fluid been used to create decaffeinated coffee?
A) Pharmaceuticals
B) Cosmetics
C) Food science
D) Microelectronics
  • 24. What happens to the density of a gas as it approaches the critical temperature?
A) The density remains constant
B) The density fluctuates unpredictably
C) The density becomes higher
D) The density decreases significantly
  • 25. What range of particle sizes can be achieved using supercritical fluids?
A) 100–10000 nm
B) 5–2000 nm
C) 10–5000 µm
D) 50–500 nm
  • 26. What is the critical pressure of carbon dioxide?
A) 7.38 MPa (73.8 bar)
B) 40 bar
C) 3.4 MPa (34 bar)
D) 570 MPa
  • 27. Which natural gas field is known for isolating fossil CO2 and using carbon storage?
A) Texas gas field
B) Sleipner gas field
C) Alaska gas field
D) North Sea gas field
  • 28. Which country has marketed high-temperature domestic water heat pumps using supercritical carbon dioxide?
A) Japan
B) China
C) South Korea
D) India
  • 29. What is the minimum pressure required to compress supercritical CO2 into a solid at certain temperatures?
A) 570 MPa
B) 7.38 MPa (73.8 bar)
C) 14,000 MPa
D) 3.4 MPa (34 bar)
  • 30. What is the main advantage of using supercritical water reactors (SCWRs)?
A) Increased fuel availability.
B) Lower operational costs.
C) Reduced radiation exposure.
D) Similar thermal efficiency gains.
  • 31. What reaction converts vegetable oil into biodiesel?
A) Transesterification
B) Oxidation
C) Fermentation
D) Hydrogenation
  • 32. What is the primary benefit of using supercritical drying in manufacturing aerogels?
A) It removes solvent without causing distortion due to surface tension.
B) It reduces the cost of materials used.
C) It speeds up the drying process significantly.
D) It enhances the mechanical strength of the aerogel.
  • 33. What type of equipment uses liquid CO2 instead of supercritical CO2 to avoid damage?
A) Biomass gasification reactors.
B) Hydrogen production facilities.
C) Supercritical fluid extraction equipment.
D) CO2-based dry cleaning equipment.
  • 34. What is one advantage of using supercritical fluids in chemical reactions?
A) They increase reaction time.
B) They eliminate the need for catalysts.
C) They are cheaper than conventional solvents.
D) Rapid diffusion accelerates diffusion-controlled reactions.
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